The standard 304304l and 316316l grades are most susceptible. How to reduce the risk of stress corrosion cracking scc the risk of stress corrosion cracking scc can be minimized through plant and equipment design. Although no stainless steel grade is totally immune to chloride scc, the relative resistance of stainless steels varies substantially. Environmental factors in the stress corrosion cracking of type 316l stainless steel and alloy 825 in chloride solutions g. Therefore, the scc concerns for spent fuel storage canisters identified in a november 2004 presentation by nuclear and. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. The use of a duplex stainless steel with molybdenum such as stainless alloys 2205 or 2507 would resist crevice corrosion and stress corrosion cracking. Stainless steel 316 and 316l grade 316 is the standard molybdenumbearing grade, second inoverall volume production to 304 amongst the austenitic stainless steels. Pitting corrosion of a stainless steel is illustrated in the figure 1. For austenitic stainless steels chlorides are the major cause of stresscorrosion cracking scc. May 27, 2011 for austenitic stainless steels chlorides are the major cause of stresscorrosion cracking scc. The actual pitting corrosion phenomenon is shown on propeller shaft of high speed craft, and the pit depth was measured with dial. This together with slightly higher stacking fault energy schramm and reed 1975 are the main reasons for better resistance of type 316316l stainless steel than type 304304l to stress corrosion cracking in sodium chloride solutions. The use of 316l would be more resistant to crevice corrosion attack.
Stress corrosion cracking scc is a common issue with many specialty alloys. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of. Stress corrosion cracking of an austenitic stainless steel. Cost is very similar, and both are durable, corrosionresistant, and a good choice for highstress situations. Environmental factors in the stress corrosion cracking of. A material failure may be accelerated by the combined effect of corrosion and mechanical stress. Alloy 316316l is molybdenumbearing austenitic stainless steel. Different kinds of corrosion on stainless steel montanstahl.
The objective of this work is to evaluate if atmospheric stress corrosion cracking can develop in stainless steel cask. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides. Ssc6mo uns n08367 is a superaustenitic 6% molybdenum alloy that exhibits far greater resistance to chloride pitting, crevice corrosion and stresscorrosion cracking than the standard 300 series and standard duplex stainless steels. The molybdenum gives 316 better overall corrosion resistant properties than grade 304, particularly higher resistance to pitting and crevice corrosion in chloride environments.
Duplex grades are usually divided into three subgroups based on their corrosion resistance. Increasing nickel content above 18 to 20% or the use of duplex, or ferritic stainless steels improves resistance to cscc. This work analysed the effect of chloride deposition on the susceptibility to atmospherically induced stress corrosion cracking aiscc of stainless steel type aisi 316l used to manufacture. Methods of minimizing chloride stress corrosion cracking. Although no stainless steel grade is totally immune. The standard 304304l and 316 316l grades are most susceptible. Naoh at temperatures up to 90 c has been elucidated. Recently, i read that austenitic stainless steels may suffer from external chloride induced stress corrosion cracking cscc when exposed to a combination of tensile stresses, chlorides, water, oxygen, and a temperature threshold.
Some 95% of 316l chemical plant equipment failures may be attributed to chloride scc. Failure analysis of corrosion on stainless steel fasteners. The higher nickel and molybdenum content in this grade allows it to demonstrate better overall corrosion resistant properties than 304, especially with regard to pitting and crevice corrosion in chloride environments. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. Susceptible alloys include 304l, 316l, 321, and 347. Grade 316 is an austenitic grade second only to 304 in commercial importance. Effects of chloride and oxygen on stress corrosion cracking. This together with slightly higher stacking fault energy schramm and reed 1975 are the main reasons for better resistance of type 316 316l stainless steel than type 304304l to stress corrosion cracking in sodium chloride solutions. The threshold temperature which the stainless steel is essentially immune to external cscc is 60 degc for aisi 316.
Corrosion behaviour of type 316l stainless steel in hot. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media. In this case, in particular, in a chloridecontaining environment, stress corrosion cracking is a potential degradation mechanism of canister failure due to formation of salt deposits and the deliquescence process epri, 2005. Atmospheric salt fog testing to evaluate chloride induced. The stress corrosion cracking scc behavior of coldworked aisi type 316l uns s31603 stainless steel ss in a concentrated lithium salt solution at elevated temperature was investigated. External chloride stress corrosion cracking of stainless. Apr 14, 2015 this safety alert highlights the issue of chloride stress corrosion cracking which has been found to affect stainless steel grade 316 316l lokring pipe connectors. Feb 18, 2004 grade 316 is the standard molybdenumbearing grade, second in importance to 304 amongst the austenitic stainless steels. Exposure to room temperature environment showed parabolic weight loss behaviour, with corrosion rates of up to 0. This mode of attack is termed stress corrosion cracking scc. Mintz1, leonardo caseres2, darrell s dunndarrell s.
It is thought to start with chromium carbide deposits along grain boundaries that leave the metal open to corrosion. This level of chloride is considered to be the limit for the 188 alloys, particularly if crevices are present. Cost is very similar, and both are durable, corrosion resistant, and a good choice for high stress situations. Chloride stress corrosion cracking in austenitic stainless. Addition of nitrite to the chloride solution, which is reported to have inhibitive influence on corrosion of stainless. This safety alert highlights the issue of chloride stress corrosion cracking which has been found to affect stainless steel grade 316316l lokring pipe connectors. Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Stress corrosion cracking scc is cracking due to a process involving conjoint corrosion and straining of a metal due to residual or applied stresses.
Chloride stress corrosion cracking cscc is a type of intergranular corrosion. Stress corrosion cracking of the aisi 316l stainless steel. Sustainability of ss 904l vs ss 316 stainless steel 904l. Although the alloys 316 and 317l are somewhat more resistant to scc than the 18 cr8 ni alloys because of their molybdenum content, they still are quire susceptible. An example is hot potable water under heat transfer conditions which permit chlorides to concentrate locally.
These alloys also offer higher creep, stress torupture and tensile strength at elevated temperature. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. Stress corrosion cracking austenitic stainless steels are susceptible to stress corrosion cracking scc in halide environments. Effect of chloride deposition on stress corrosion cracking of. In this case, in particular, in a chloride containing environment, stress corrosion cracking is a potential degradation mechanism of canister failure due to formation of salt deposits and the deliquescence process epri, 2005. The 304 and 304l 188 stainless steel alloys have been utilized very successfully in fresh waters containing low levels of chloride ion of up to 100 ppm. Prior cold deformation of the structure under load increases the risk of stress corrosion cracking. Chloride stress corrosion cracking and 316 stainless steel moltenmetal chemical 20 jul 11 07. This is particularly apparent for pitting and crevice corrosion in chloride. Stress corrision cracking is a relatively rare form of corrosion, which requires a specific combination of tensile stress, temperature and corrosive species, often the chloride ion, for it to occur. Their mixed microstructure provides improved resistance to chloride stress corrosion cracking in comparison to austenitic stainless steel types 304 and 316. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Atmospheric salt fog testing to evaluate chloride induced stress corrosion cracking of type 304, 304l, and 316l stainless steel todd s.
The combination of tensile stress and a specific corrosive environment can crack stainless steels. The corrosion behaviour of type 316l stainless steel in aqueous 3050 wt%. To that end, types 304, 304l, and 316l stainless steel ubend samples were fabricated and placed in an environmental chamber. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. The cracking has occurred in the driver swage ring section of the connector as shown. Austenitic stainless steels chloride induced stress. Alloy 904l is a superaustenitic stainless steel that is designed for moderate to high corrosion resistance in a wide range of process environments. Cold work of materials, dissolved oxygen and chloride in water are crucial factors that accelerate the stress corrosion cracking scc crack growth rate of stainless steel in high temperature water. Higher levels of chloride might cause crevice corrosion and pitting.
However, molybdenum itself does not get incorporated in the passive film. The most common type is transgranular stress corrosion cracking, scc, which. Chloride stress corrosion cracks were also found at the corrosion sites. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. Stress corrosion cracking of an austenitic stainless steel in. Alloy ssc6mo superaustenitic stainless steel sandmeyer. Corrosion of stainless steel type 316l in a seepage water. Cragnolino 1 center for nuclear waste regulatory analyses, southwest research institute, 6220 culebra road, san antonio, tx, 782385166. Stress corrosion cracking of stainless steel plate and nickel. Effects of cold work on stress corrosion cracking of type. Two examples of such processes are stress corrosion cracking and corrosion fatigue.
These alloys also offer higher creep, stresstorupture and tensile strength at elevated temperature. Stress corrosion cracking and hydrogen embrittlement of type. This article describes the susceptibility of 316l stainless steel to stress corrosion cracking scc in a nitritecontaining chloride solution. Chloride stress corrosion cracking inspectioneering. Effects of marine environments on stress corrosion cracking. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Chloride stress corrosion involves selective attack of a metal along its grain boundaries. Scc is known as an insidious form of corrosion failure and it results in a significant drop in the mechanical strength only with little metal loss. A precursor of stress corrosion cracking in chloride bearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting.
The stress corrosion cracking scc behavior of coldworked aisi type 316l uns s31603 stainless steel ss in a concentrated lithium. Simulated sea salt was deposited on the surface of the samples, using a salt fog procedure. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Chloride stress corrosion cracking and 316 stainless steel. Types 316 and 316l are molybdenumbearing austenitic stainless steel which are more resistant to general corrosion and pittingcrevice corrosion than the conventional chromium nickel austenitic stainless steel such as type 304. Stress corrosion cracking of the aisi 316l stainless steel haz in a pwr nuclear reactor environment. But even though it has less carbon, 316l is very similar to 316 in almost every way. With its highly alloyed chemistry 25% nickel and 4. Sour service limits of dualcertified 316316l steel twi. Introduction one of the most accepted mechanisms of stress corrosion cracking scc i.
Scc can occur typically in hot water tanks or swimming pools. Chloride stress corrosion cracking in austenitic stainless steel. With watch brands like ball starting to use 904l stainless steel, taking the bragging rights away from rolex, we thought now is the perfect time to explore the differences between 316l and 904l at least when it comes to watches. Corrosion of stainless steel by hot caustic research using solutions of chemically pure caustic sodium hydroxide naoh led to the development of a diagram that attempts to delineate the param eters of concentration and tem perature governing stress corrosion cracking scc of type. Austenitic stainless steel may be susceptible to chloride stress corrosion cracking cscc. Effect of chloride deposition on stress corrosion cracking of 316l stainless steel used for intermediate level radioactive waste containers. A precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting.
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